Bruno Schuler, Shadi Fatayer, et al.
Energy and Fuels
The Diels–Alder reaction is one of the most popular reactions in organic chemistry. However, its use in the field of on-surface synthesis is hampered by the spatial restrictions of this cycloaddition reaction. Herein we selected a cyclic strained triyne to demonstrate an on-surface hexadehydro-Diels–Alder reaction in a single molecule. The reaction was studied in detail by means of atomic force microscopy (AFM) with CO-functionalized tips. Our results pave the way to use this iconic pericyclic reaction for on-surface synthesis, introducing the concept of atom economy in the field.
Bruno Schuler, Shadi Fatayer, et al.
Energy and Fuels
Bruno Schuler, Yunlong Zhang, et al.
Chemical Science
Lukas Z. Kastner, Dominik Peller, et al.
CLEO 2021
Shadi Fatayer, Nimesh B. Poddar, et al.
JACS