Michael R. Philpott, Iven Pockrand, et al.
The Journal of Chemical Physics
With the aid of computer techniques, including a laboratory automation system, accurate computer simulation, and an accurate calculation method, the EPR spectrum of copper doped in zinc fluoride has been analyzed. The observed g values led by a new method to a determination of the coefficients of the Kramer's doublet. Copper hyperfine structure verified these values and fluorine transferred hyperfine structure gave a measure of covalency. The fractional orbital occupation showed predominantly σ bonding which is similar to other reported transition metal ions in ionic insulating crystals. Orbital reduction, though no doubt present, makes only an insignificant and undetectable contribution.
Michael R. Philpott, Iven Pockrand, et al.
The Journal of Chemical Physics
Michael R. Philpott, J.D. Swalen
The Journal of Chemical Physics
A. Skumanich, M. Jurich, et al.
OTF 1993
H. Gugger, M. Jurich, et al.
Physical Review B