J. Pacansky, Joachim Bargon
JACS
The ESR spectrum of the 2-pentafluorophenylallyl radical in solution is reported. It shows splittings from the fluorine substituents in addition to the usual allyl hyperfine splittings. Extensive CNDO/INDO calculations indicate that at the equilibrium geometry the allyl and phenyl planes are twisted by about 65°, and further allow an interpretation of the unusual fluorine Isotropic coupling constants in terms of π- as well as of σ-electron mechanisms. © 1979 American Chemical Society.
J. Pacansky, Joachim Bargon
JACS
Robert J. Waltman, Joachim Bargon, et al.
Journal of Physical Chemistry
Robert J. Waltman, Joachim Bargon
Journal of Electroanalytical Chemistry
Joachim Bargon, F. Graf, et al.
Journal of Physical Chemistry