Generation and pyrolysis of a cyclopropyl substituted cyclopentadiene: A potential source of unsaturated annelated cyclopentanones

Robert D. Miller

doi:10.1039/C39760000277

Journal of the Chemical Society, Chemical Communications

Paper

01 Dec 1976

Generation and pyrolysis of a cyclopropyl substituted cyclopentadiene: A potential source of unsaturated annelated cyclopentanones

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Abstract

The tertiary allylic alcohol (2) is readily dehydrated by catalytic amounts of non-aqueous acid to the cyclopentadiene derivative (3), which is subsequently regiospecifically transformed to the vinyl sulphide (6) by pyrolysis.

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