Mani Abedini, Michael Kirley, et al.
Australasian Medical Journal
The photolysis of 2-cyanofuran in alcohols yields 1-alkoxy-2-cyanocyclopropane-3-carboxaldehydes as the major products, which rearrange thermally to trans-2-alkoxy-3-cyano-2,3-dihydrofurans and small amounts of cis-isomers. Thermal mutual rearrangements between trans- and cis-2- alkoxy-3-cyano-2, 3-dihydrofurans were studied. Liquid phase thermal addition of alcohols in a temperature range between 100° and 200° yields 1-alkoxy-1-(2-furan)-methylenimines, which rearrange photochemically to 2-furyl-methylamino-ketone in case of the methoxy derivative. 3-Cyano-furan does not yield photoaddition or thermal addition products. The different behaviors of 2- and 3-substituted furans are discussed. © 1973.
Mani Abedini, Michael Kirley, et al.
Australasian Medical Journal
Wilhad Reuter, Allen Lurio
Nuclear Instruments and Methods
A. Shabo
Current Opinion in Molecular Therapeutics
Tiziana Mordasini, Alessandro Curioni, et al.
ChemBioChem