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Potential methods for atomic layer epitaxy growth of Si using halogenated silane precursors are discussed. One method uses alternating exposures of Si2H6 and Si2Cl6. This method deposits "new" Si (Si*) on Si(100) as demonstrated through the attenuation of a boron "marker" layer. Another method uses self-terminating adsorption of SiClH3 or SiCl2H2 at about 500°C, followed by exposure to atomic H. Only the initial adsorption step of this method is studied here. © 1993.
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EMC 2011
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